SYNTHESIS AND CHARACTERIZATION OF SOME METAL COMPLEXES WITH IEA AS LIGAND DERIVED FROM 2-ACETLYLINDAN-1,3-DIONE
The present investigation are based on the synthesis and characterization of metal complexes with Schiffâ€™s bases (anils) Indenoâ€“ethylidene aniline (C17H13O2N), (IEA), (L1H) derived from 2-substituted acetyl 1, 3 - dione by condensing it with primary aryl amine (aniline) in absolute alcohol. The Co (II), Ni(II), Cu (II), Zn (II), Cd (II), Fe (III), V (III) and Cr (III) complexes of the Schiffâ€™s bases have been prepared in the reactions and investigated their structures by physicodemical methods. The formulation and structure of the ligands have been screened by their chemical analysis, IR, PMR and mass-spectral studies. The structure of the anils has been characterized by their IR spectra which showed strong absorption at 1705, 1650 and 1570 cm-1 along with other bands. The structure of ligand has been confirmed by their massâ€“spectral studies.Keywords: Metal Complexes, Schiffâ€™s bases, 2-Acetlylindan-1,3-Dione
Authors who publish with this journal agree to the following terms:
- Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported License. that allows others to share the work with an acknowledgment of the work's authorship and initial publication in this journal.
- Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgment of its initial publication in this journal.
- Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work (SeeÂ The Effect of Open Access).