Synthesis and Evaluation of Cr (III), Mn (III) and Fe (III) Schiff Base of Metals Complexes

  • Kalpataru Halder Department of Biochemistry, Sri Satya Sai University of Technology & Medical Sciences, Sehore-466001, Madhya Pradesh
  • Utpal Saha Department of Biochemistry, Sri Satya Sai University of Technology & Medical Sciences, Sehore-466001, Madhya Pradesh
DOI https://doi.org/10.22270/jddt.v9i3.2609

Abstract

A novel synthesized Schiff base metal complexes Cr (III), Mn (III) and Fe (III) of 2-hydroxy-5-chloro acetophenone 2-imino-4-phenyl thiazole were prepared by condensed from 2-hydroxy-5-chloro acetophenone and 2-amino-4-phenyl thiazole have been synthesized and characterized on the basis of elemental analysis, Infrared, 1H NMR, molar conductance and magnetic susceptibilities analysis. The Schiff base acts as a monobasic bidentate ligand commonly coordinates through the oxygen atom of phenolic OH group and the nitrogen atom of azomethine group, which is confirmed by IR spectral data. All the metal complexes have studies thermal properties and their thermal parameter.


Keyword: Schiff base, Magnetic, Thermal studies.

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Author Biographies

Kalpataru Halder, Department of Biochemistry, Sri Satya Sai University of Technology & Medical Sciences, Sehore-466001, Madhya Pradesh

Department of Biochemistry, Sri Satya Sai University of Technology & Medical Sciences, Sehore-466001, Madhya Pradesh

Utpal Saha, Department of Biochemistry, Sri Satya Sai University of Technology & Medical Sciences, Sehore-466001, Madhya Pradesh

Department of Biochemistry, Sri Satya Sai University of Technology & Medical Sciences, Sehore-466001, Madhya Pradesh

References

1. Canali L, Sherrington DC. Chem Soc Rev 1999; 28:52.
2. Prasad KS, ShivaKumar L, Chandan S, Jayalakshmi B, Revanasiddappaa HD. Spectrochim. Acta, Part A, 2011; 81:276.
3. Kumar S, Dhar D, Saxena P, J Sci and Indu Research 2009; 68:181.
4. Hawlader MB, Begum MS. Indian J Chem 2004; 43A: 2352.
5. Sharma RP, Kothari AK, Sharma NK. Indian J Derm Vener Lepr 1995; 61:26.
6. Ballchausen CJ, Gray HB. Inorg Chem 1962; 1:11.
7. Furniss BS, Hannaford AJ, Smith PWG, Tatchell AR. Vogel’s practical organic chem. Edn 5, Logman Scientific Technical, John Wiley and Sons 1989.
8. Vogel AI. A Text book of quantitative inorganic chemistry, Edn 3, ELBS, London, 1961.
9. Maurya MR, Gopinathan C. Indian J Chem 1996; 35A: 701.
10. Jayaramadu M, Reddy KH. Indian J Chem 1999; 38A: 1173.
11. Sastry PS, Rao TR. Proc Indian Acad Sci 1995; 107(1):25.
12. Mahajan RK, Patial VP. J Indian Council Chem 2001; 18(1):4.
13. Maurya MR, Antony DC, Gopinathan S, Gopinathan C. Bull Chem Soc Jpn 1995; 68:554.
14. Viroopakshapp J, Vithalrao D. J Indian Chem Soc 1996; 73:531.
15. Figgis BN. “Introduction to ligand field”, weley Estern Ltd., 1976.
16. Sacconi L. J Ame Chem Soc 1954; 76:3400.
17. Panda AK, Dash DC, Mishra P, Mohnaty H. J Indian Chem Soc 1996; 35A:324.
18. Mallikarjun K. E J Chem 2004; 1(2):105.
19. Horowitz H, Metzger G. Anal Chem 1963; 35:1464.
20. Broido A. J Polym Sci 1964; A2:1761.
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How to Cite
1.
Halder K, Saha U. Synthesis and Evaluation of Cr (III), Mn (III) and Fe (III) Schiff Base of Metals Complexes. JDDT [Internet]. 15May2019 [cited 22Jan.2021];9(3):114-6. Available from: http://jddtonline.info/index.php/jddt/article/view/2609
Issue
Vol 9 No 3 (2019): Volume 9, Issue 3, May-June 2019
Section
Research
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